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MSE PRO [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)– MSE Supplies LLC

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MSE PRO [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane, >98% - MSE Supplies LLC

MSE PRO [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane, >98%

SKU: CM1112

  • $ 000

MSE PRO™[1,1′-Bis(diphenylphosphino)ferrocene]

dichloropalladium(II), complex with dichloromethane, >98%

MSE PRO [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane, >98% is frequently used as a catalyst for pharmaceutical and pesticide synthesis. It is also a popular choice for isomerization, as well as transverse coupling reactions including Suzuki, Sonogashira, Heck, Negishi, and Stille couplings. Additionally, it is a valuable resource for processes involving carbonylation, oxidation, and carbon-carbon bond formation.

Technical Specifications:

CAS No. 95464-05-4
MDL No. MFCD00792899
Chemical Name [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane
Synonym(s)
  • Pd(dppf)Cl2 · CH2Cl2
  • Pd(dppf)Cl2 · DCM

  • [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (1:1)
Chemical Formula C35H30Cl4FeP2Pd
Package
  • CM1112: 5g
  • CM1113: 10g
  • CM1114: 25g
  • CM1115: 100g
Molecular Weight 816.64 g/mol
Purity >98%
Melting Point 275-280°C
Appearance Orange-red powder
Storage Room temperature, air and heat sensitive, need to protect from light, stored under nitrogen

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References 

[1] Cvengroš, Ján, et al. "Electrophilic Activation of Benzaldehydes through ortho Palladation: One‐Pot Synthesis of 3‐Methylene‐indan‐1‐ols through a Domino Allylstannylation/Heck Reaction under Neutral Conditions." Angewandte Chemie 121.33 (2009): 6264-6267.

[2] Monot, Julien, et al. "Suzuki− Miyaura Coupling of NHC− Boranes: A New Addition to the C− C Coupling Toolbox." Organic Letters 11.21 (2009): 4914-4917.

[3] Thiel, Oliver R., et al. "Palladium‐Catalyzed Coupling of Aldehyde‐Derived Hydrazones: Practical Synthesis of Triazolopyridines and Related Heterocycles." Angewandte Chemie 122.45 (2010): 8573-8576.

[4] Chiba, Shunsuke, Yan-Jun Xu, and Yi-Feng Wang. "A Pd (II)-catalyzed ring-expansion reaction of cyclic 2-azidoalcohol derivatives: synthesis of azaheterocycles." Journal of the American Chemical Society 131.36 (2009): 12886-12887.