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MSE PRO [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)– MSE Supplies LLC

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MSE PRO [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), Pd(dppf)Cl<sub>2</sub>, >98% - MSE Supplies LLC

MSE PRO [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), Pd(dppf)Cl2, >98%

SKU: CM1092

  • $ 000

MSE PRO™ [1,1'Bis(diphenylphosphino)ferrocene] dichloropalladium(II), Pd(dppf)Cl2, >98%

MSE PRO [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), Pd(dppf)Cl2, boasts a purity of >98% and is frequently used as a catalyst for pharmaceutical and pesticide synthesis. It is also a popular choice for isomerization, as well as transverse coupling reactions including Suzuki, Sonogashira, Heck, Negishi, and Stille couplings. Additionally, it is a valuable resource for processes involving carbonylation, oxidation, and carbon-carbon bond formation.

Technical Specifications:

CAS No. 72287-26-4 
EC No. 460-040-3
MDL No. MFCD00015757
Chemical Name [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
Synonym(s)
  • Pd(dppf)Cl2
  • Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II)

  • 1,1'-Bis(diphenylphosphino)ferrocene palladium(II)dichloride
Chemical Formula C34H28Cl2FeP2Pd
Package
  • CM1092: 5g
  • CM1093: 10g
  • CM1094: 25g
  • CM1095: 100g
Molecular Weight 731.70g/mol
Purity >98%
Melting Point 266-283°C
Appearance Red powder
Storage 2-8°C, air and heat sensitive, need to protect from light, stored under nitrogen

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References:

[1] Cvengroš, Ján, et al. "Electrophilic Activation of Benzaldehydes through ortho Palladation: One‐Pot Synthesis of 3‐Methylene‐indan‐1‐ols through a Domino Allylstannylation/Heck Reaction under Neutral Conditions." Angewandte Chemie 121.33 (2009): 6264-6267.

[2] Monot, Julien, et al. "Suzuki− Miyaura Coupling of NHC− Boranes: A New Addition to the C− C Coupling Toolbox." Organic Letters 11.21 (2009): 4914-4917.

[3] Thiel, Oliver R., et al. "Palladium‐Catalyzed Coupling of Aldehyde‐Derived Hydrazones: Practical Synthesis of Triazolopyridines and Related Heterocycles." Angewandte Chemie 122.45 (2010): 8573-8576.

[4] Chiba, Shunsuke, Yan-Jun Xu, and Yi-Feng Wang. "A Pd (II)-catalyzed ring-expansion reaction of cyclic 2-azidoalcohol derivatives: synthesis of azaheterocycles." Journal of the American Chemical Society 131.36 (2009): 12886-12887.