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MSE PRO 3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]palladium(II)– MSE Supplies LLC

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MSE PRO (1,3-Bis(2,6-diisopropylphenyl)-1H-imidazol-2(3H)-ylidene) chloro(cinnamyl)palladate(II), ≥98.0% Purity - MSE Supplies LLC

MSE PRO (1,3-Bis(2,6-diisopropylphenyl)-1H-imidazol-2(3H)-ylidene) chloro(cinnamyl)palladate(II), ≥98.0% Purity

SKU: CM1422

  • $ 54995

MSE PRO™ (1,3-Bis(2,6-diisopropylphenyl)-1H-imidazol-2(3H)-ylidene) chloro(cinnamyl)palladate(II), ≥98.0% Purity

MSE PRO™ (1,3-Bis(2,6-diisopropylphenyl)-1H-imidazol-2(3H)-ylidene)chloro(cinnamyl)palladate(II) is a highly versatile and robust organometallic complex that has garnered significant attention in the field of homogeneous catalysis. This palladium(II) compound features a unique structural motif, incorporating a strongly donating N-heterocyclic carbene (NHC) ligand derived from 1,3-bis(2,6-diisopropylphenyl)imidazolium, which imparts exceptional stability and reactivity to the metal center. The presence of the cinnamyl ligand, along with the chloride co-ligand, renders this complex an ideal precatalyst for a wide range of transformations, including cross-coupling reactions, olefin metathesis, and other valuable synthetic protocols.

MSE Supplies offers various catalysts and ligands of coupling reaction. Please contact us for customization or bulk orders.

Technical Specifications:

CAS No. 884879-23-6
Chemical name (1,3-Bis(2,6-diisopropylphenyl)-1H-imidazol-2(3H)-ylidene)chloro(cinnamyl)palladate(II)
Synonym(s)
  • Chloro[(1,2,3-η)-3-phenyl-2-propenyl][1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]palladium(II)

  • 3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]palladium(II)
Chemical formula C36H45ClN2Pd
Pack size 5 g (CM1422)
Molecular weight 647.63 g/mol
Purity ≥98.0%
Melting point 205-208 °C
Appearance Light yellow to yellow solid
Storage temperature 2-8°C, protect from light, stored under nitrogen


References:

[1] Türkmen, H., & Çetinkaya, B. (2006). 1, 3-Diarylimidazolidin-2-ylidene (NHC) complexes of Pd (II): Electronic effects on cross-coupling reactions and thermal decompositions. Journal of organometallic chemistry, 691(18), 3749-3759.

[2] Ray, L., Shaikh, M. M., & Ghosh, P. (2007). Air-stable, convenient to handle Pd based PEPPSI (pyridine enhanced precatalyst preparation, stabilization and initiation) themed precatalysts of N/O-functionalized N-heterocyclic carbenes and its utility in Suzuki–Miyaura cross-coupling reaction. Dalton Transactions, (40), 4546-4555.