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MSE PRO Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)– MSE Supplies LLC

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MSE PRO Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)(Pd(dppe)<sub>2</sub>, ≥97.0% Purity - MSE Supplies LLC

MSE PRO Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) (Pd(dppe)2), ≥97.0% Purity

SKU: CM1423

  • $ 35995

MSE PRO™ Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) (Pd(dppe)2), ≥97.0% Purity

MSE PRO™ Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) is a commonly abbreviated as Pd(dppe)2, is an important organometallic complex widely used as a catalyst precursor in various organic transformations. The dppe ligand (1,2-bis(diphenylphosphino)ethane) is a bidentate chelating diphosphine that forms a stable 14-electron complex with the Pd(0) center. It is a versatile precatalyst for various cross-coupling reactions (e.g., Suzuki, Heck, Stille) and other Pd-catalyzed transformations due to the lability of the dppe ligands.

MSE Supplies offers various catalysts and ligands of coupling reaction. Please contact us for customization or bulk orders.

Technical Specifications:

CAS No. 31277-98-2
Chemical name Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
Synonym(s)
  • Bisbisdiphenylphosphinoethanepalladium

  • Bis(ethylenebis(diphenylphosphine))palladium
Chemical formula C52H48P4Pd
Pack size 10 g (CM1423)
Molecular weight 903.25 g/mol
Purity ≥97.0%
Melting point 219-225 °C
Appearance Light yellow to brown solid
Storage temperature -20°C, stored under nitrogen


References:

[1] Wang, L., Yu, Y., Razgoniaev, A. O., Johnson, P. N., Wang, C., Tian, Y., ... & Widenhoefer, R. A. (2020). Mechanochemical regulation of oxidative addition to a palladium (0) bisphosphine complex. Journal of the American Chemical Society, 142(41), 17714-17720.

[2] Breit, N. C., Szilvasi, T., Suzuki, T., Gallego, D., & Inoue, S. (2013). From a zwitterionic phosphasilene to base stabilized silyliumylidene-phosphide and bis (silylene) complexes. Journal of the American Chemical Society, 135(47), 17958-17968.