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MSE PRO (R)-BINAP-Pd(II)Cl2, ≥99.0% Purity– MSE Supplies LLC

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MSE PRO ((R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)dichloropalladium((R)-BINAP-Pd(II)Cl<sub>2</sub>, ≥99.0% Purity - MSE Supplies LLC

MSE PRO ((R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)dichloropalladium ((R)-BINAP-Pd(II)Cl2), ≥99.0% Purity

SKU: CM1411

  • $ 18995

MSE PRO™ ((R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)dichloropalladium((R)-BINAP-Pd(II)Cl2), ≥99.0% Purity

MSE PRO™ ((R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)dichloropalladium also known as (R)-BINAP-Pd(II)Cl2, is a widely used chiral palladium catalyst in organic synthesis. It is a highly efficient and selective catalyst for various cross-coupling reactions, such as the Suzuki-Miyaura, Stille, Heck, Sonogashira, and Buchwald-Hartwig couplings. This compound plays a crucial role in catalyzing asymmetric reactions for carbon-carbon and carbon-heteroatom bond formation. It is commonly used in the enantioselective synthesis of chiral biaryl compounds, heterocycles, and natural products.

MSE Supplies offers various catalysts and ligands of coupling reaction. Please contact us for customization or bulk orders.

Technical Specifications:

CAS No. 115826-95-4
Chemical name ((R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)dichloropalladium
Synonym(s)
  • [(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II) chloride

  • 2,2'-Bis(diphenylphosphino)-1,1'-binaphthylpalladium(II) chloride

  • (R)-BINAP-Pd(II)Cl2
Chemical formula C44H32Cl2P2Pd
Pack size

5 g (CM1411)
10 g (CM1412)
Molecular weight 800.00 g/mol
Purity ≥99.0%
Optical activity [α]24/D +682°, c = 0.5 in chloroform
Appearance Light yellow to yellow solid
Storage temperature 2-8°C, protect from light, stored under nitrogen

References:

[1] Chatterjee, S., George, M. D., Salem, G., & Willis, A. C. (2001). Optically active asymmetric di (tertiary phosphines). Crystal and molecular structure of [SP-4-3-(SP, S)]-{1-[(2-chlorophenyl) methylphosphino]-2-(dimethylphosphino) benzene-P, P′}{1-[1-(dimethylamino) ethyl] naphthyl-C 2, N} palladium (II) hexafluorophosphate. Journal of the Chemical Society, Dalton Transactions, (12), 1890-1896.

[2] Jaillet, A., Darcel, C., Bayardon, J., Schlachter, A., Salomon, C., Rousselin, Y., ... & Jugé, S. (2020). Design of P-chirogenic aminophosphine–phosphinite ligands at both phosphorus centers: origin of enantioselectivities in Pd-catalyzed allylic reactions. The Journal of Organic Chemistry, 85(22), 14391-14410.