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MSE PRO Bis(triphenylphosphine)dichloropalladium, Pd(PPh3)2Cl2, >98%– MSE Supplies LLC

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MSE PRO Bis(triphenylphosphine)dichloropalladium, Pd(PPh<sub>3</sub>)<sub>2</sub>Cl<sub>2</sub>, >98% - MSE Supplies LLC

MSE PRO Bis(triphenylphosphine)dichloropalladium, Pd(PPh3)2Cl2, >98%

SKU: CM1104

  • £000
  • Save £20600

MSE PRO™ Bis(triphenylphosphine)dichloropalladium,

Pd(PPh3)2Cl2, >98%

MSE PRO Bis(triphenylphosphine)dichloropalladium, Pd(PPh3)2Cl2, has various applications including hydrogenation, hydrosilylation, carbonylation, oxidation, elimination, reduction, allyl acetate isomerization, 1,3-diene dimerization, and C-C bond formation (e.g. Negishi coupling, Suzuki coupling, Kumada coupling , Sonogashira coupling, Heck coupling) and Sonogashira-Hagihara coupling reactions. It is also commonly used in the preparation of tetrakis(triphenylphosphine)palladium, condensed heterocycles such as furanquinoline, diphenyl acetylene, and other compounds.

Technical Specifications:

CAS No. 13965-03-2
EC No. 237-744-2
MDL No. MFCD00009593
Chemical Name Bis(triphenylphosphine)dichloropalladium
Synonym(s)
  • Pd(PPh3)2Cl2

  • Dichlorobis(triphenylphosphine)palladium(II)
Chemical Formula C36H30Cl2P2Pd
Package
  • CM1104: 5g
  • CM1105: 10g
  • CM1106: 25g
  • CM1107: 100g
Molecular Weight 701.90 g/mol
Purity >98%
Melting Point 260°C
Appearance Yellow powder
Storage 2-8°C, air and heat sensitive, need to protect from light, stored under nitrogen

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References 

[1] Walton, Barbara L., et al. "Imidazolium salts with varying anions as charge carriers for detection of neutral bis (triphenylphosphine) palladium (II) dichloride in electrospray ionization mass spectrometry." Rapid Communications in Mass Spectrometry 27.17 (2013): 1954-1960.

[2] Bharathiraja, Ganesan, et al. "Expedient synthesis of tetrasubstituted pyrroles via a copper-catalyzed cascade inter-/intramolecular cyclization of 1, 3-enynes carry a nitro group with amines." Organic & Biomolecular Chemistry 13.9 (2015): 2786-2792.

[3] Imoto, Hiroaki, et al. "Color Tuning of the Aggregation‐Induced Emission of Maleimide Dyes by Molecular Design and Morphology Control." Chemistry–A European Journal 21.34 (2015): 12105-12111.

[4] Djekić, T., Aloysius GJ van der Ham, and A. B. de Haan. "Evaluation of functionalized silica's for the adsorptive recovery of homogenous catalysts through interaction with the metal centre." Journal of chromatography A 1142.1 (2007): 32-38.